Safety Data Sheet Anhydrous citric acid - Sucroal (2025)

Safety Data Sheet
ANHYDROUS CITRIC ACID

SECTIÓN 1. PRODUCT IDENTIFICATION

1.1 GHS Product Identifier
ANHYDROUS CITRIC ACID
This SDS applies to the following product presentations: granular, fine and extra fine, solution grade.

1.2. Others mean of identification
• Ácid 2-hidroxi 1,2,3-propanotricarboxílico.
• Beta hydroxytricarboxylic acid.Número
• CAS: 77-92-9.
• EC Number: 201-069-1

1.3 Recommended use of the chemical and restrictions.
Industrial use: additive and preservative in the food industry, raw material in the production of citrates (calcium
citrate, magnesium citrate, potassium citrate, sodium citrate, zinc citrate), acidifier and pH regulator. NOT suitable
for domestic use or other applications. It is NOT a food.

1.4 Supplier information
SUCROAL S.A.
Km 18 Straight Cali Palmira deviation Candelaria 1 Km
00000 Palmira – Valle – Colombia
Phone: (+062) 4310500
info@sucroal.com.co
www.sucroal.com.co
SUCROAL S.A.
Phone: ( 57) 3102563315 (24 hours 7 day )
Phone: (0672) 4310774 (Monday a Friday, 8am – 5pm)

SECTION.2 PRODUCT IDENTIFICATION

2.1 Classification of the substance or mixture
Serious eye damage/eye irritation (Category 2A)

2.2 GHS label elements, including precautionary statements

WARNING
Causes serious eye irritation
Precautionary statements
Wear eye and face protection equipment.
Store only in original container.
Keep container tightly closed.
Avoid dispersion and accumulation of dust.
Keep away from heat, hot surfaces, sparks, open flames and other sources of ignition. No Smoking.
Take precautionary measures against electrostatic discharge.
Grounding and equipotential bonding of the container and the receiving equipment.
Use explosion-proof equipment, electrical material, ventilation and lighting.
Do not use tools that produce sparks.
Do not eat, drink or smoke while handling the product.
Wash hands and face thoroughly after handling.
Store in a cool, well-ventilated, explosion-proof place.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses when present and can be
done easily. Continue with the wash.
See an ophthalmologist immediately.
In case of contact or exposure, call a doctor if the person feels unwell.

2.3 Other hazards that do not lead to a classification
May form explosive dust-air mixture if dispersed.

SECTIÓN 3. COMPOSITION/INFORMATION ON INGREDIENTS

Citric acid (77-92-9)
Additional Information
Does not apply.

3.2 Mixtures:
N/A

SECTION 4. FIRST AID

4.1 Description of necessary first aid
INHALATION
Transport person to fresh air and keep in a position that facilitates breathing.
INGESTION
DO NOT induce vomiting. Rinse mouth with water and spit out. Give to drink one or two glasses of water in small
proportions. Caution: never give anything by mouth to an unconscious person.
SKIN CONTACT
Remove all contaminated clothing. Rinse skin with plenty of water or shower for at least 15 minutes. DO NOT apply
creams or ointments. Wash contaminated clothing before reuse.
EYE CONTACT
Immediately flush with a gentle but abundant stream of water for at least 15 uninterrupted minutes, separating the
eyelids with the fingers. If applicable, remove contact lenses, if it can be done easily. continue washing.

4.2 Most important symptoms/effects, acute and delayed
The main symptoms are redness of the eyes, tearing, blurred vision and itching sensation in the affected part of the
body. The only known acute effect of the product is reversible eye irritation. There are no known possible delayed
effects of the product.

4.3 Indication of the need to receive immediate medical attention and, where appropriate, special treatment
In case of contact with eyes, see an ophthalmologist immediately. In case of contact or exposure, seek medical
attention if the person feels unwell. Bring the tag or a photo of it. Follow supportive and symptomatic treatment
according to the person’s condition.

SECTION 5. FIRE-FIGHTING MEASURES

5.1 Appropriate Extinguishing Media
Foam, dry chemical or halon (considering also the surrounding fire).
If water is used, it should be applied in overflowing amounts in spray or mist form.

5.2 Specific hazards of the chemical
May form explosive dust-air mixture if dispersed in confined spaces. During combustion, toxic fumes of carbon
monoxide and carbon dioxide may be produced.
In a solid state, dust particles can increase the probability of explosion in confined spaces.

5.3 Special measures to be taken by fire fighting teams
Extinguish fire from a safe distance If the fire is outdoors or in a drafty area, always face the wind at your back,
never head on. If the situation warrants, wear an encapsulating suit with self-contained breathing apparatus
(SCBA) to prevent contact with high concentrations of airborne vapors or fumes. Move unaffected containers from
the fire area, if it can be done safely. Avoid dispersion of the product in the air. Prevent the waste generated in the
fire from reaching the drains.

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Use recommended PPE (see Section 8). Isolate the contaminated area. Avoid dispersion of the product. Keep
away from heat, ignition sources, sparks and open flames. No Smoking. Do not use tools that produce sparks.

6.2 Environmental precautions
Keep away from drains, surface and ground water. Dispose of used material and product residues in such a way
that they do not represent a danger to people or the environment (see Section 13). Spills of large quantities in
water or soil must be reported to the competent authorities.

6.3 Methods and materials for containment and cleaning of spills
DO NOT spread the product. Small spills can be controlled by absorbing the product with absorbent cloths
moistened with water. Large spills can be controlled by vacuuming or by wet methods. Do not sweep or control spill
by blowing. Do not use combustible materials such as sawdust. Collect immediately in stainless steel containers
with tight lids. Ultimately, clean the affected area with water.

6.4 Reference to other sections:
See sections 8 and 13.

SECTIÓN 7. MANIPULATION AND STORAGE

7.1 Precautions to be taken to ensure safe handling
Use recommended PPE (see Section 8). Store only in original container. Keep container tightly closed, when not in
use and when transporting. Avoid dispersion and accumulation of dust. DO NOT use in confined spaces. Open the
container slowly, avoiding dispersing the product Preserve the bags containing the product. Do not sift, grind, grind
or any other operation that decreases the particle size and generates dust dispersion. Keep away from heat, hot
surfaces, sparks, open flames and other sources of ignition. No Smoking. Take precautionary measures against
electrostatic discharge. Grounding and equipotential bonding of the container and the receiving equipment. Ideally
transfer in closed explosion-proof systems. When pouring, avoid free pouring from the container. Use explosionproof equipment, electrical material, ventilation and lighting. Do not use tools that produce sparks. Keep the
workplace clean and orderly. DO NOT sweep or blow, vacuum or use wet methods to clean. Store the product in
the original container, do not transfer to another container. If it is necessary to transfer, do so in a stainless steel
container and remember to label. DO NOT mix with incompatible substances (see Section 10). DO NOT use for
other purposes (NOT suitable for domestic use). Do not eat. Keep away from food and drinks. DO NOT eat, drink
or smoke when handling this product. Change contaminated clothing before leaving work and wash before reuse.
Wash hands and face thoroughly after handling and before eating, drinking or smoking. Dispose of contents and
packaging in accordance with Section 13.

7.2 Conditions for safe storage, including any incompatibilities
Store in a cool, well-ventilated area, ideally with localized exhaust. Keep away from heat, moisture, sources of
ignition and incompatible substances (see Section 10). Recommended storage temperature: greater than or equal
to 5oC. Maximum storage time: 2 years. Store only in the original container, tightly closed. Store in stainless steel
containers. Once the containers are opened, close hermetically and in an upright position to avoid spillage. Protect
the container and label from physical damage.

7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding
the uses of this product.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters
The ACGIH® TLV® and BEI® values are protected by copyright.
Danger group (control banding): A.

8.2 appropriate engineering controls
A general ventilation system is recommended to prevent the accumulation of dust in the air and/or localized
extraction with an anti-explosion system. In general, a localized exhaust system is preferred because it can control
emissions at their source, preventing their dispersal into the work environment. Have facilities and equipment with
anti-explosion systems. Have electrostatic discharge control systems. Have detection systems and fire
extinguishing equipment. Have eyewash fountains close to the places where the product is used.

8.3 Individual protection measures, such as personal protective equipment (PPE)
Eye protection:
Wear a face shield or glasses with a full frame (monoglasses).

Hand protection:
Wear nitrile rubber gloves (minimum thickness 0.8 mm).

Body protection:
Wear natural fiber or antistatic clothing, without outer pockets. Wear safety shoes for chemical agents, with
antistatic protection. In the event of spills, it may be necessary to wear a protective suit against chemical agents.

Respiratory protection:
Not required under normal use conditions.
In the event of a spill, use a full face mask with a particle filter with a minimum efficiency of 95%.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES AND SAFETY CHARACTERISTICS

Physical state: Solid
White color
Smell: odorless
Melting point / freezing point: 153ºC
Boiling point or initial boiling point and boiling range: not available
Flammability: Combustible Dust
Upper and lower explosion/flammability limits: not applicable
Flash point: not applicable
Autoignition temperature: not applicable
Decomposition temperature: 175ºC
pH: 1.5-1.6 at 20ºC (10% w/w in water)
Kinematic viscosity: not applicable
Solubility: 750 g/l (20ºC)
Partition coefficient n-octanol/water: -1.57
Vapor pressure: not applicable
Density and/or relative density: 1.66 g/cm3 (18ºC, aqueous solution)
Relative vapor density: not applicable
Particle characteristics: not applicable
Particle size:

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity
May form explosive dust-air mixture if dispersed.
Information for the product in solution: can attack metals.

10.2 Chemical stability
Stable under normal conditions of temperature and pressure. Stable in contact with light and humidity. May form
explosive dust-air mixture if dispersed. Thermally decomposes at 175°C.

10.3 Possibility of hazardous reactions
It reacts exothermically (releasing large amounts of heat), in contact with oxidizing agents, bases, reducing agents
and metals.

10.4 Conditions to Avoid
Dispersion and accumulation of the product in the air. Lockdown. Heat, hot surfaces, open flames, sparks,
electrostatic discharge, and other sources of ignition. Very dry atmospheres.

10.5 incompatible materials
Oxidizing agents, bases, reducing agents, metals.

10.6 Hazardous decomposition products
Methyl maleic anhydride.

SECTION 11. TOXICOLOGICAL INFORMATION

The classification was made based on the result of the acute inhalation toxicity test and the information available in
reliable databases for the product. The only known acute effect of the product is reversible eye irritation. There are
no known chronic effects of the product. Symptoms associated with product exposure are described in Section 4.

Likely routes of exposure
Ingestion, skin/eye exposure, inhalation.

ACUTE TOXICITY
LD50 (oral, rats) = 11,700 mg/kg (equivalent to OECD 401)
LD50 (dermal, rats) > 2,000 mg/kg (equivalent to OECD 402)
LC50 (inhalation, rats) > 5 mg/l, 4 hours (OECD 433)
SKIN CORROSION/IRRITATION
Mean value equal to 0 for erythema/eschar and for edema in the six animals tested (rabbit), at 24, 48 and 72 hours
after patch removal (OECD 404).

SERIOUS EYE DAMAGE/EYE IRRITATION
Mean value equal to 0 for opacity of the cornea and iritis and greater than 2 for redness and edema of the conjunctiva, in the three animals tested (rabbit), at 24, 48 and 72 hours after removing the patch. Effects reversible
after 14 days of trial (OECD 404).

RESPIRATORY OR SKIN SENSITIZATION
Not a skin sensitizer, in a test on guinea pigs (OECD 406).

GERM CELL MUTAGENICITY
Not available.

CARCINOGENICITY
Product not included in the IARC classification list.

REPRODUCTIVE TOXICITY
Not available.

SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY – SINGLE EXPOSURE
Not irritating to the respiratory tract and not narcotic, according to the results of the acute inhalation toxicity test in
rats (OECD 433).

SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY – REPEATED EXPOSURE
Not available.

ASPIRATION HAZARD
Based on the product properties, the product is not hazardous by aspiration.

OTHER INFORMATION
Not available.

SECTIÓN 12. ECOTOXICOLOGICAL INFORMATION

The classification was made from the information available in reliable databases for the product. The product is not
expected to be acutely toxic to the aquatic environment, to be persistent, or to bioaccumulate in the environment.
No other information available.

12.1 Toxicity
LC50 (Leuciscus idus melanotus, 48 h) = 440 mg/l (OECD 203)

12.2 Persistence and degradability
Readily biodegradable: 97%, 28 days (OECD 301 B)

12.3 Bioaccumulative potential
Log Kow < 0 (see section 9)

12.4 Mobility in soil
Not available.

12.5 Other Adverse Effects
Not available.

SECTIÓN 13. INFORMATION REGARDING THE DISPOSAL OF THE PRODUCTS

13.1 Disposal methods
Dispose of contents and container in accordance with local regulations. Empty containers retain product residue
and can be dangerous. Handle the container and its contents with due care (see Section 7). Use, mixtures or contamination may change the options for the disposal of this product. Recycle plastic and paper bags, if possible.
Do not use empty bags to contain food or for domestic purposes. Large quantities of product, plastic bags and
paper bags that cannot be recycled must be delivered to an authorized hazardous waste manager. Final disposal
method for the product: landfill (prior neutralization of the product). Final disposal method for bags: incineration.

SECTIÓN 14. INFORMATION REGARDING TRANSPORTATION

14.1 Númber ONU
Not applicable.

14.2 UN proper shipping name
Not applicable.

14.3 Transport Class(es)
Not applicable.

14.4 Packing group/packaging if applicable
Not applicable.

14.5 Environmental risks
Does not apply.

14.6 Special precautions for user
Preserve the bags during loading, transport and unloading, in order to avoid breaking the bags and dispersing the
product (consider the size and weight of the bags). Carry out loading and unloading operations in well-ventilated
areas. Wear eye protection.

14.7 Transport in bulk according to annex II of MARPOL 73/78 and the IBC Code
Does not apply.

14.8 With regard to IMDG 39-18:
Does not apply.

SECTIÓN 15. REGULATORY INFORMATION

15.1 Specific provisions on safety, health and environment for the product in question
international provisions
Product not subject to the Montreal Protocol, Stockholm Convention, Rotterdam Convention, Minamata
Convention.
Provisions applicable to Colombia
• Decree 1496/2018. Ministry of Labor.
• Resolution 773/2021. Ministry of Labor.
• Decree 4741/2005. Ministry of Environment, Housing and Territorial Development

15.2 US federal regulations
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication Standard, 29 CFR
1910.1200. All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.

SARA 304 Emergency release notification
Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.

Toxic Substances Control Act (TSCA)
Superfund Amendments and Reauthorization Act of 1986
(SARA) SARA 302 Extremely hazardous substance
Not listed.

SARA 311/312 Hazardous chemical YES
Classified hazard categories Combustible dust
Categories Serious eye damage or eye irritation
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated

Safe Drinking Water Act (SDWA) Contains component(s) regulated under the Safe Drinking Water Act.
Food and Drug Total food additive
Administration (FDA) Direct food additive
GRAS food additive

US state regulations
US. Massachusetts RTK – Substance List
Not regulated.
US. New Jersey Worker and Community Right-to-Know Act
Not listed.
US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.
US. Rhode Island RTK

International Inventories

*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

SECTIÓN 16. OTHER INFORMATION

This Safety Data Sheet was prepared in accordance with the 6th revised edition of the GHS (2015) and Regulation
No. 773/2021 of the Ministry of Labor of Colombia, (applies to regulations for Colombia).
Additionally, it is generated with the 2012 communication guidelines. 29 CFR 1910.1200
Abbreviations used
ACGIH®: American Conference of Governmental Industrial Hygienists.
BEI®: Biological Exposure Indices.
CAS: Chemical Abstract Service.
CL: Lethal concentration.
LD: lethal dose.
EC: European Commission.
PPE: Personal Protection Equipment.
SDS: Safety Data Sheet.
IARC: International Agency for Research on Cancer.
OECD: Organization for Economic Cooperation and Development.
GHS: Globally Harmonized System of classification and labeling of chemical products.
TLV®: Threshold Limit Values.

Hazard Statement Codes
[H319] Causes serious eye irritation

NFPA 704 Classification

next review: 02/04/2028

SUCROAL S.A. provides the information contained herein in good faith, but neither the company nor its
representatives are responsible for its accuracy or completeness, nor do they make any express or implied
warranty or guarantee, including without limitation warranty of merchantability or fitness for a particular purpose
with respect to to the information set forth in this document or to the product to which the information relates. This
document is intended to be a guide only for handling the material with appropriate caution by a person suitably
trained in the use of this product. Before using this substance it is the responsibility of the user of this SDS to verify
the information contained herein. Consequently, SUCROAL S.A: and its representatives will not be responsible for
the damages caused by the use of the product relying on this information or for subjective interpretations given to
this safety data sheet. The fact of possessing this SDS indicates that the previous declarations are accepted